Dr. Stephen J. Loeb
Chemistry & Biochemistry



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Windsor, ON Canada N9B 3P4
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University of Windsor



LoebResearchGroup
Publications 1981 - 1990
24. B. de Groot, S. J. Loeb, "Simultaneous Co-ordination of the Endodentate and Exodentate Conformations of a Crown Thioether Ligand to a Single Metal Centre. Synthesis and Structure of [Ag(TT[9]OB)2][CF3SO3], (TT[9]OB = 2,5,8-Trithia- [9]-o-benzenophane)." J. Chem. Soc., Chem. Commun. 1990, 1755-1757.

23. B. de Groot, S. J. Loeb, " Crown Thioether Ligands Containing Rigid Xylyl Units. Synthesis and Structures of 2,5,8-Trithia[9]-o-benzenophane, (TT[9]OB), 2,5,8-Trithia[9]-m-benzenophane, (TT[9]MB) and Mo(CO3)(TT[9]OB)." Inorg. Chem. 1990, 29, 4084-4090.

22. H. A. Jenkins, S. J. Loeb, D. G. Dick, D. W. Stephan, "Dihydride Formation Versus H2-Loss in the Protonation of the Heterobimetallic FePt Complex (CO)3Fe(µ-H)-(µ-PCy2)Pt(PEt3)2." Can. J. Chem. 1990, 68, 869-874.

21. B. de Groot, S. J. Loeb, "Synthesis and Structure of the Crown Thioether 1,3,6,9,11,14-Hexathiacyclohexadecane, (16S6), and the Cu(I) Complex [Cu(16S6)][ClO4]." Inorg. Chem. 1989, 28, 3573-3578.

20. H. A. Jenkins, S. J. Loeb, "Synthesis and Reaction Chemistry of the Heterobimetallic FeIr Complexes (CO)3(PPh3)Fe(µ-PCy2)Ir(PPh3)(CO)2 and (CO)4Fe(µ-PCy2)Ir(1,5-COD)." Can. J. Chem. 1989, 67, 1230-1235.

19. H. A. Jenkins, S. J. Loeb, D. W. Stephan, "Synthesis and Reaction Chemistry of the Coordinatively Unsaturated Heterobimetallic Complexes (CO)3(PPh3)Fe(µ-PCy2)Rh(PPh3)(CO) and (CO)4Fe(µ-PCy2)Rh(1,5-COD). Crystal and Molecular Structure of (CO)3(PPh3)Fe(µ-PCy2)Rh(PPh3)(CO)." Inorg. Chem. 1989, 28, 1998-2003.

18. H. A. Jenkins, S. J. Loeb, N. T. McManus, "(CO)(PEt3)ClIr(µ-PCy2)2IrCl(PEt3)(CO), A Phosphido-Bridged Bimetallic Ir(II) Complex." Inorg. Chim. Acta, 1989, 159, 83-86.

17. K. J. Beckett, S. J. Loeb, "Mononuclear Rh, Ir, Pd, and Pt Complexes of the Tripod Ligand (PPh2)3CH. Molecular Structure of [Bis(1,1,1-tris(diphenylphosphino)methane) platinum(II)] tetrafluoroborate." Can. J. Chem. 1988, 66, 1073-1080.

16. S. J. Loeb, H. A. Taylor, L. Gelmini, D. W. Stephan, "Heterobimetallic Dicyclohexylphophido-Bridged Complexes of MoNi, MoPd, MoPt, WNi, WPd, and WPt. Crystal and Molecular Structure of (CO)4Mo(µ-PCy2)2Pd(PPh3)." Inorg. Chem. 1986, 25, 1977-1982.

15. E. Konefal, S. J. Loeb, D. W. Stephan, C. J. Willis, "Coordination Modes of Polydentate Ligands. 4. The Crystal and Molecular Structure of an Oxo-Bridged Iron(III) Complex Containing a Pentadentate Imino-Alkoxy Ligand." Inorg. Chim. Acta, 1986, 115, 147-151.

14. M. Cowie, I. R. McKeer, S. J. Loeb, M. D. Gauthier "Diazoalkane Activation by Iridium Phosphine Complexes. 2. Unusual Products Resulting from N2-Loss form the Dibenzoyldiazomethane Ligand: Structures of [IrCl(HC(C(O)Ph)2)(PC6H4Ph2)(PPh3)]. 1/2C6H5CH3 and [IrCl(C6H4)(C(O)C-C(Ph)OPPh2)(PPh3)2].C6H5CH3." Organometallics 1986, 5, 860-868.

13. M. Cowie, S. J. Loeb, I. R. McKeer "Diazoalkane Activation by Iridium Phosphine Complexes. 1. Complexes Containing the Intact Dibenzoyldiazomethane Ligand and Interconversion Between h1-N-Bound and a Chelated N,O-Bound Form of the Ligand Accompanied by Hydride Migration. Organometallics 1986, 5, 854-859.

12. M. Cowie, S. J. Loeb, "Structure of [Rh2(CO)2(µ-tBuC2)(Ph2PCH2PPh2)2][ClO4]: An 'A-frame' Compound Containing a s-p-Acetylido Group." Organometallics 1985, 4, 852-857.

11. L. Gelmini, S. J. Loeb, D. W. Stephan, "The Molecular Structure of Rh2Cl2(µ-CO)(µ-(C6H5)2PCH2P(C6H5)2)2.2C6H6: A Rhodium 'A-frame' Complex." Inorg. Chim. Acta, 1985, 98, L3-L6.

10. S. J. Loeb, D. W. Stephan, C. J. Willis, "Coordination Modes of Polydentate Ligands. 2. The Template Synthesis of Four-, Five, and Six-Coordinate Fluorinated Schiff-Base Complexes of Ni2+; the Structure of an Octahedral Ni2+ Complex Containing Two Tridentate Ligands." Inorg. Chem. 1984, 23, 1509-1512.

9. E. Konefal, S. J. Loeb, D. W. Stephan, C. J. Willis, "Coordination Modes of Polydentate Ligands. 1. Template Synthesis of Complexes of Ni2+, Cu2+, and Co2+ with Pentadentate and Hexadentate Ligands: Structure of a Highly Distorted Six-Coordinate Co2+ Complex." Inorg. Chem. 1984, 23, 538-545.

8. M. Cowie, M. D. Gauthier, S. J. Loeb, I. R. McKeer "Unexpected Ortho-metalated Products Resulting From Dibenzoyldiazomethane Activation in the Presence of Iridium Phosphine Complexes" Organometallics 1983, 2, 1057-1059.

7. S. J. Loeb, J. R. Richardson, C. J. Willis, "Synthesis, Absolute Configuration, and Magnetic Properties of Some Copper(II) Complexes of Chiral, Bidentate and Tridenate Fluorinated Amino Alkoxy Ligands" Inorg. Chem. 1983, 22, 2736-2743.

6. S. J. Loeb, C. J. Willis, "Synthesis and Magnetic Properties of Some Chiral Tetranuclear Imino-Alkoxy Complexes of Copper(II)." Inorg. Chem. 1981, 20, 2791-2794.

5. D. L. Barber, S. J. Loeb, J. W. L. Martin, N. C. Payne, C. J. Willis, "Fluorinated Alkoxides XVI. The Structure of a Dinuclear Iminoalkoxy Complex of Cu2+" Inorg. Chem. 1981, 20, 272-275.

4. J. H. Timmons, J. W. L. Martin, A. E. Martell, P. Rudolf, A. Clearfield, S. J. Loeb, C. J. Willis " The Crystal and Molecular Structure of Di-µ-9,9,9-Trifluoro-8-Trifluoromethyl-6- methyl- 5-azanon-5-ene-1,8-Dialoto(2-)-O,N,O'-Dicopper(II), Cu2C20H26F12N2O4 and Di-µ-8,8,8-Trifluoro-7-Trifluoro-methyl-4-methyl-4-azaocta-4-ene-1,7-Dialoto(2-)-O,N,O'-Dicopper(II),Cu2C18H22F12 N2O4. The Effects of Varying Chelate Ring Size on Geometry and Antiferromagnetic Exchange in Di-µ-oxobridged Dinuclear Copper(II) Complexes." Inorg. Chem. 1981, 20, 181-186.

3. J. H. Timmons, J. W. L. Martin, A. E. Martell, P. Rudolf, A. Clearfield, J. H. Arner, S. J. Loeb, C. J. Willis, "The Template Synthesis and the Crystal and Molecular Structure of Bis[1,1,1,12,12,12-Hexafluoro-2,11-di(trifluoromethyl)-4,9-dimethyl-2,11-dialoto(2-)-5,8-diazadodeca-4,8-diene] Cerium(IV), CeC28H28F24N4O4. A Fluorinated Schiff-Base Complex of Eight Coordinate Cerium(IV)." Inorg. Chem. 1980, 19, 3553-3557.

2. S. J. Loeb, J. W. L. Martin, C. J. Willis, "Fluorinated Alkoxides XV. Synthesis and Hydrogenation of Iminoalkoxy Complexes of Copper(II). Influence of Chelate Ring Size on Structure and Magnetic Properties" Inorg. Chem. 1979, 18, 3160-3163.

1. S. J. Loeb, J. W. L. Martin, C. J. Willis "Fluorinated Alkoxides XII. Studies on Potentially Tridentate Fluorinated Diols; Zwitterionic and Five-Coordinate Complexes of Ni2+ and Cu2+." Can. J. Chem. 1978, 56, 2369-2373.